The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing. A key question is the nature of irradiationassisted intergranular cracking at very high dose, i. Pitting resistance is also superior in comparison to types 304 and 316. Characterization of intergranular stress corrosion. Film and ph effects in the stress corrosion cracking of. The corrosion data in this section is mainly based on the results of general corrosion laboratory tests, which are not strictly comparable with actual service conditions. Pdf chloride induced stress corrosion cracking of type 304. Stainless steel grade 304 cs 304 304l technical data. For more information, please check 304 vs 316 stainless steel. The presence of 23 wt% molybdenum in the alloy makes the passive film stronger kain et al. There is an additional risk of stress corrosion cracking scc at higher temperatures. Film and ph effects in the stress corrosion cracking of type.
Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. It has excellent forming and welding characteristics. Chloride stress corrosion cracking in austenitic stainless. Type 321 stainless steel offers higher creep and stress rupture properties than type 304 and, particularly, type 304l which might also be considered for exposures where sensitization and intergranular corrosion are concerns. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the insulation industry. The general level of corrosion resistance of ak steel 2205 duplex is superior to types 304 and 316 in most cases. Although most research has been done on the mechanism of igscc, little is known. The datasheet and specification are summarized in the following tables including. Effect of halogens and inhibitors on the external stress. The combination of the high molybdenum and chromium content, along with the. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
The lower carbon content minimizes chromium carbide precipitation due to welding and its susceptibility to intergranular corrosion. Austenitic stainless steels crni types 304, 304l, 321, and similar and crnimo types 316, 316l, 316 ti, and similar are susceptible to atmosphericallyinduced stress corrosion cracking. The author explains this by relating it to the austenitic steel properties, such as coefficient of thermal expansion, thermal conductivity and elevated flow stress, or with the simpler hardnessstrength distribution observed in stainless steels that are welded in an annealed condition when compared to fsw highstrength aluminium alloys. Aisi 304 grade stainless steel uns s30400 aisi 304 stainless steel uns s30400 is the most commonly used material in stainless steels, and is usually purchased in an annealed or cold worked.
Reference is often made to stainless steel in the singular sense as if it were one material. Analysis of a 25yearold 304 stainless steel handhole gasket from a. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The effect of alloying elements and how these elements affect the electrochemical response in 50% naoh environments can be assessed, by comparing individual alloy responses. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367. Inhibition of stress corrosion cracking in 304 stainless.
Deterioration by clscc can lead to failures that have the potential to release. Influence of high temperature on corrosion behavior of 304. Type 304 stainless steel is highly susceptible to scc in chloride solution as demonstrated by the. Effects of fluoride and other halogen ions on the external.
Aisi 304l is the low carbon version of 304 stainless steel, aisi 316 is better than grade 304 in certain properties, corrosion resistance and heat resistance, etc. Summary of available data for estimating chlorideinduced scc. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. What forms of corrosion can occur in stainless steels. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing.
The type 321 austenitic stainless steel is susceptible to stress corrosion cracking scc in halides similar to type 304 stainless steel. Stainless steel 304 has excellent corrosion resistance in a wide variety of environments and when in contact with different corrosive media. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Corrosion behaviour of type 316l stainless steel in hot.
It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. Stresscorrosion cracking of sensitized type 304 stainless. Stainless steel 304l an overview sciencedirect topics. This paper presents a fusion welding process that was developed for snf canister repair. This results because of their similarity in nickel content. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Chloride stress corrosion cracking in austenitic stainless steel. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l. Stainless steel grade 304 is an austenitic, corrosion resistant steel with excellent strength, toughness, fabrication characteristics and weldability.
Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stainless steels stainless 304 properties, fabrication. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The chloride ion cl is the most common of these and is found in everyday materials such as salt and. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Type 439 is a titanium stabilized, 18 percent chromium alloy that may be used in many oxidizing environments where type 304 is considered adequate in terms of general corrosion resistance but is. This work explores the fate of the coupling current generated during stress corrosion cracking of sensitized type 304 stainless steel 304ss in thiosulfate solution at ambient temperature. Pitting and crevice corrosion can occur in environments containing chlorides. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. Conditions which cause stress corrosion cracking are. Atmospheric stress corrosion cracking of stainless steel. Stress corrosion cracking of sensitized type 304 stainless. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially. Grade 304 is the most commonly used stainless steel. From the wealth of research data on rapid causticscc of stainless steel, it is clear. Ss304 grade aisi 304 stainless steel properties, composition. Coldworked 304 stainless steels ss are known to be susceptible to stress corrosion cracking scc. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Written especially for design engineers, it presents an overview of a broad range of stainless steels both standard and proprietary their compositions.
It is an austenitic, corrosion resistant steel with excellent strength, toughness, fabrication characteristics and weldability. This study employs atomprobe tomography apt for local chemical analysis of the oxides formed. Abstract intergranular stress corrosion cracking igscc of austenitic stainless steels and nickel base alloys continues to be a major problem in light water reactors. Rapid stress corrosion cracking of 304 stainless steel in mgcl 2fecl 3 solutions at 125 c has been shown to occur only when the ph of the corrodent liquid within the crack lay between 1. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Slow strain rate tests ssrts were conducted on 304 steel in.
Therefore, standard grades such as 304304l and 316316l are very susceptible to this mode of attack. Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. The resistance of austenitic stainless steels to scc is related to the nickel content of the steel. Pdf stress corrosion cracking of stainless steel components in. Stainless steel datasheets revised november 2011 page 1 of 1 au austenitic stainless steels 301, 301l, 301ln high strength for roll formed structural components 302hq low. It is also referred to as 188 stainless steel, a2 stainless steel as per the iso 3506, or 304s15 as per the. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media. Pitting or crevice corrosion can occur on most stainless steel grades. Chloride stress corrosion cracking ssina specialty steel. The type 302, 304, 304l and 305 alloys are the most susceptible of the austenitic stainless steels to stress corrosion cracking in halides because of their relatively low nickel content. Pdf chloride stress corrosion cracking scc of type 304 and.
Below 80 degc they can be considered resistant to any concentration of sodium hydroxide, up to the. Corrosion and corrosion properties of stainless steels. Nuregcr7030, atmospheric stress corrosion cracking. This mode of attack is termed stress corrosion cracking scc. To fill this need, the committee of stainless steel producers initially prepared this booklet. Stress corrosion cracking scc of duplex stainless steel. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Most notably, pitting and cracking in this instance had initiated andor. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i.
The interaction of corrosion fatigue and stresscorrosion. The effects of titanium ion implantation on the stress corrosion cracking scc behaviour of 304 austenitic stainless steel were studied. Our data bases and mechanistic understanding of the degradation of such highly irradiated components, however, are not well established. Stress corrosion cracking scc is a common issue with many specialty alloys. Grade 304 stainless steel is the most versatile and the most widely used of all stainless steels. Design guidelines for the selection and use of stainless steel nidl distributed by. Chloride stress corrosion cracking inspectioneering. Hence the tendency for stress corrosion cracking of the plain 304 or 316 stainless steels in solution annealed condition is not considered to be different from its low carbon varieties. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. The low carbon version, 304l, may be required for full corrosion resistance when thicker sections are welded.
Sensor requirements for detection and characterization of. Improved resistance to pitting corrosion in chloride environments. Figure 1 shows data on the susceptibility of type 304 stainless steel to stress corrosion cracking under certain conditions. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. Stress corrosion cracking susceptibility of 304l substrate. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to. Figure 3 shows two microstructures of type 304 stainless steel. Preventing stress corrosion cracking of austenitic stainless steels in. Formability formability of ak steel 2205 duplex is better than. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Stabilised grades for heavy section welding and high temperature applications. Stress corrosion cracking of an austenitic stainless steel in. Alloy c276 nickel alloy plate has excellent corrosion resistance in both oxidizing and reducing environments. Type 321 stainless steel s also advantageous for high temperature service because of its good mechanical properties. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances.
Ak steel 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. Type 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. Autoclave experiments on a set of samples withwithout coldwork prior to oxidation, and withwithout stress applied during oxidation, were carried out under simulated pressurised water reactor. Stress corrosion cracking of sensitized stainless steel type 304 in. Rapid stress corrosion cracking of 304 stainless steel in mgcl 2fecl 3 solutions at 125 c has been shown to occur only when the ph of the corrodent liquid within the crack lay. Detecting and imaging stress corrosion cracking in. Summary of available data for estimating chlorideinduced scc crack growth rates for. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Pdf chloride induced stress corrosion cracking of type 304 and. The potential for stress corrosion cracking scc of welded stainlesssteel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Type 304 stainless steel an overview sciencedirect topics.
The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic. The saeansi 304 aisi 304 is the most commonly available and used type of stainless steel. Both 304 and 316 stainless steel types are resistant to a wide range of concentration and temperature. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Causticinduced scc can occur in breweries where concentrated caustic solutions.
Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular. Stress corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Stress corrosion cracking resistance is superior to the austenitic grades of stainless steel. Stress corrosion cracking of an austenitic stainless steel. C 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. Stainless steels are more resistant to general corrosion compared with carbon steel.
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